A Dual‐Mode Electrochromic Platform Integrating Zinc Anode‐Based and Rocking‐Chair Electrochromic Devices

The complementary electrochromic device, where the optical transmittance changes upon the flow of cations back and forth between anodic and cathodic electrodes, operates in a rocking‐chair fashion if it can inherently self‐discharge. Herein, the first demonstration of a dual‐mode electrochromic platform having self‐coloring and self‐bleaching characteristics is reported, which is realized by sandwiching zinc metal within a newly‐designed Prussian blue (PB)‐WO3 rocking‐chair type electrochromic device. It is demonstrated that the redox potential differences between the zinc metal and the WO3/PB electrodes endow the self‐color‐switching of these electrodes. By employing a hybrid electrolyte of Zn2+/K+, it is further shown that the colored PB‐WO3 rocking‐chair device is capable of spontaneously bleaching when the anodic and cathodic electrodes are coupled. This dual‐mode light‐control strategy enables the electrochromic devices to exhibit four distinct optical states with the highest optical contrast of 72.6% and fast switching times (<5 s for the bleaching/coloration processes). Furthermore, the built‐in voltage of the dual‐mode electrochromic devices not only promotes energy efficiency, but also augments the bistability of the devices. It is envisioned that the broad implication of the present platform is in the development of self‐powered smart windows, colorful displays, optoelectronic switches, and optical sensors.