Electromagnetic Absorption Mechanism of TPMS‐Based Metastructures: Synergy Between Materials and Structures

3D metastructure absorbers have gained attention for their lightweight, load‐bearing capabilities, and superior electromagnetic wave absorption. However, the complex interplay between unit cell geometry, material properties, and electromagnetic response is not well understood, hindering the design of high‐performance devices. A multi‐scale model, validated is presented by simulations and experiments, that clarify the relationship between materials, structures, and electromagnetic behavior in 3D metastructures. By systematically investigating strut‐based and sheet‐based structures, volume fraction, unit size, crystal lattice orientation, and density gradient within TPMS‐based unit cells, it is revealed that unit geometry significantly influences electromagnetic field propagation and reflection loss. Specifically, under the same unit size, sheet‐based TPMS metastructures exhibit stronger reflectivity than strut‐based ones, while multilayer structures show the opposite trend. The direct correlation is also further confirmed between geometric symmetry and polarization insensitivity, with orthogonal isotropic superstructures displaying excellent polarization‐insensitive properties. This finding provides a new design principle for achieving robust, angle‐independent absorption in these materials. This work enhances understanding of the structure‐electromagnetic behavior interplay, guiding the design of next‐generation broadband, wide‐angle, and polarization‐insensitive devices.