Fullerene Bisadducts for Enhanced Open‐Circuit Voltages and Efficiencies in Polymer Solar Cells
Martijn Lenes, Gert‐Jan A. H. Wetzelaer, Floris B. Kooistra, Sjoerd C. Veenstra, Jan Cornelis Hummelen, Paul W. M. Blom
University of Groningen Dutch Polymer Institute Zernike Institute for Advanced Materials Energy Research Centre of the Netherlands
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摘要与影响
A fullerene bisadduct can enhance the efficiency of polymer:fullerene bulk heterojunction solar cells. The bisadduct has a LUMO that is 100 meV higher compared to that of [6,6]-phenyl C61 butyric acid methyl ester (PCBM). This increases the open-circuit voltage of polymer:fullerene bulk heterojunction solar cells based on poly(3-hexylthio phene) and bisadduct PCBM to 0.73 V, while maintaining high fill factors and currents.
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Conducting polymers and applications · Fullerene Chemistry and Applications
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