General Design Concept for Single‐Atom Catalysts toward Heterogeneous Catalysis

As a new and popular material, single-atom catalysts (SACs) exhibit excellent activity, selectivity, and stability for numerous important reactions, and show great potential in heterogeneous catalysis due to their high atom utilization efficiency and the controllable characteristics of the active sites. The composition and coordination would determine the geometric and electronic structures of SACs, and thus greatly influence the catalytic performance. Based on atom economy, rational design and controllable synthesis of SACs have become central tasks in the fields of low-cost and green catalysis. Herein, an introduction to the recent progress in the precise synthesis of SACs including the regulation of the coordination structure and the choice of different systems is presented. Thereafter, the potentials of SACs in different applications are comprehensively summarized and discussed. Furthermore, a detailed discussion of the recent developments regarding the large-scale preparation of SACs is provided, including the major issues and prospects for industrialization. Finally, the main challenges and opportunities of rapid large-scale industrialization of SACs are briefly discussed.