Iridium‐Catalyzed Asymmetric Hydrogenation of 3‐Substituted 2H‐1,4‐Benzoxazines
Kai Gao, Chang‐Bin Yu, Duo‐Sheng Wang, Yong‐Gui Zhou
Dalian Institute of Chemical Physics Chinese Academy of Sciences State Key Laboratory of Catalysis Shanghai Institute of Organic Chemistry
阅读操作
确认中在文库中上传 PDF 后可生成中文音频讲解。
摘要与影响
The highly enantioselective hydrogenation of 3‐aryl‐2H‐1,4‐benzoxazines was achieved using the (cyclooctadiene)iridium chloride dimer/(S)‐SegPhos/iodine {[Ir(COD)Cl]2/(S)‐SegPhos/I2} system as catalyst with up to 92% ee. The 3‐styryl‐2H‐1,4‐benzoxazine derivatives were also hydrogenated by the iridium catalyst and Pd/C in two consecutive steps whereby 93–95% ee values were obtained.
逐年被引趋势
关键指标
同类平均 = 1
同领域 · 同年份 · 同类型
Google Scholar 与 OpenAlex 的被引统计范围不同，数值存在差异属正常。
AI 辅助阅读
依据：摘要
可就本文提问；依据不足时会说明。
学术脉络
学科主题
化学Asymmetric Hydrogenation and Catalysis
Asymmetric Synthesis and Catalysis · Nanomaterials for catalytic reactions
参考文献 105
此处列出前 3 条
引用本文 57
按被引量排序，此处列出前 3 条