Deformable Eutectic Alloy With Near‐Theoretical Yield Strength via Hierarchical Nanoscale Multiphases and Sessile Defects

Eutectic high‐entropy alloys (EHEAs), a typical bioinspired lamellar composite, have the potential to achieve high strength and good ductility simultaneously for structural applications through microstructure modification. However, an extreme modulus/hardness mismatch between constituent phases leads to premature fracture and severely limits the achievable yield strength by impeding plasticity at room temperature. Here, a CoCrFeNiTa 0.4 EHEA designed via suction casting followed by precise thermal treatment, which exhibits sessile interface defects and hierarchical nano‐multiphase structures consisting of FCC‐Laves eutectic lamellae, L1 2 and D0 22 coprecipitates, attains a near‐theoretical yield strength of 2.6 GPa alongside sufficient plasticity of 13.6%. This breakthrough is attributed to multiple mechanisms, characterizing soft‐FCC nanolamellae strengthened by coherent L1 2 precipitates, sessile planar faults, and misfit‐interface dislocations, while hard‐Laves nanolamellae are toughened by deformable D0 22 precipitates. All of these factors lead to the reduced modulus/hardness mismatch between FCC and Laves lamellae. The results indicate that the long‐range modulus/hardness‐matching and short‐range heterostructure, via hierarchical multiple phases and defects, are pivotal for next‐generation dual‐ and multi‐phase alloys to achieve theoretical strength while retaining impressive plasticity.