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Correspondence on “Water‐Derived Radical Species Initiate Six‐Electron Oxidation of Cyclic Ketones in Microdroplets” Angew. Chem. Int. Ed . 2026, e1888676
Willem Hendrik Koppenol
ETH Zurich
来源Angewandte Chemie International Edition
年份2026
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Cooks and coworkers ( Angewandte Chemie 65 (2026), e1888676, https://doi.org/10.1002/anie.1888676 ) claim that cyclic ketones are oxidized by H 2 O •+ . Formation of this species requires a substantial input of energy to be formed and is, even if it were to be formed, too short‐lived to participate in bimolecular reactions.
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化学Oxidative Organic Chemistry Reactions
Radical Photochemical Reactions · Free Radicals and Antioxidants
参考文献 5
Observation of the fastest chemical processes in the radiolysis of water
被引 293Zhi-Heng Loh, Gilles Doumy, C. Arnold · Science · 2020
Electric buzz in a glass of pure water
被引 116Dor Ben‐Amotz · Science · 2022
Comment on “Radical-mediated proton transfer enables hydroxyl radical formation in charge-delocalized water” by R. Zhao, Q. Zhang, N. Yang, L. Li, Z. Li and C. Cui, Chem. Sci. , 2025, 16 , 11954
被引 2Willem Hendrik Koppenol · Chemical Science · 2026
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