Cooperative Iron–Brønsted Acid Catalysis: Enantioselective Hydrogenation of Quinoxalines and 2 <i>H</i>‐1,4‐Benzoxazines

Come together! A selective Fe-catalysed enantioselective reduction of quinoxalines and benzoxazines with hydrogen is demonstrated. Key to success is the combination of a chiral Brønsted acid and a well-defined non-chiral Fe hydrogenation catalyst. This methodology constitutes an attractive and environmentally favourable alternative to well-established asymmetric hydrogenations by using precious-metal-based catalysts.