Unconventional Photo‐Control of Structural Features Using Elliptically Polarized Light

The holographic interference of either same‐handed or orthogonal polarized beams is commonly employed in the fabrication of optical elements as it enables the development of an ideal sinusoidal surface modulation by inducing the mass migration of photochromic polymer. However, this approach encounters challenges in producing multiplexed optical elements with a complex surface topography, primarily due to only sinusoidal surface topography which limits control over the feature's shape and size. Here, a versatile approach is demonstrated for fabricating spatially multiplexed optical elements using ellipticity‐controlled orthogonally elliptically polarized (OEP) beams that offer distorted square‐like and rhombus‐like pillars on the azopolymer layer by asymmetric azopolymer migration driven by spatially varying ellipticity and azimuth angle of interference beam. These multiplexed distorted shapes enable selective energy transfer during light diffraction and also induce a phase‐shift to polarization states. Ellipticity control of both writing and interference beams provides an additional degree of freedom for structuring the surface topography of optical elements. Furthermore, a quantitative analysis of the multiplexed OEP surface relief is performed to achieve distinct diffraction properties, thereby rendering its suitability for fabricating complex optical elements.