研究论文
A New, Convenient Synthesis of the Linear Phosphazene Salt [Cl3PNPCl3]Cl: Preparation of Higher Linear Homologues [Cl3PN−(PCl2N)xPCl3]Cl (x = 1−3) and the 16-Membered Macrocycle [NCCl(NPCl2)3]2
Eric Rivard, Alan J. Lough, Ian Manners
University of Toronto
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摘要与影响
摘要 · 完整
An improved synthetic route to the linear phosphazene salt [Cl3P=N=PCl3]Cl is reported. This species is a useful precursor to higher linear homologues and also to heterocycles such as the 16-membered carbophosphazene macrocycle [NCCl(NPCl2)3]2.
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学术脉络
学科主题
化学Synthesis and characterization of novel inorganic/organometallic compounds
Organophosphorus compounds synthesis · Phosphorus compounds and reactions
参考文献 34
Chemistry of Boratophosphazenes: Synthesis of Borazine-Phosphazene Hybrid Cations, and New Inorganic Heterocycles by Skeletal Substitution Reactions
被引 31Derek P. Gates, A.R. McWilliams, Ralf Ziembinski · Chemistry - A European Journal · 1998
N-trimethylsilyl-trichlorphosphinimin
被引 31Edgar Niecke, Wolfhelm Bitter · Inorganic and Nuclear Chemistry Letters · 1973
The preparation of linear phosphonitrilic chlorides
被引 27Edward Moran · Journal of Inorganic and Nuclear Chemistry · 1968
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引用本文 31
Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N 3 P 3 Cl 6 ] catalyzed by silylium ions
被引 79Yun Zhang, Keith Huynh, Ian Manners · Chemical Communications · 2007
Probing the Mechanism of the PCl5−Initiated Living Cationic Polymerization of the Phosphoranimine Cl3P═NSiMe3 using Model Compound Chemistry
被引 56Vivienne Blackstone, Alan J. Lough, Martin Murray · Journal of the American Chemical Society · 2009
Unified Approach to Imidodiphosphate-Type Brønsted Acids with Tunable Confinement and Acidity
被引 49Sebastian Armin Schwengers, Chandra Kanta De, Oleg Grossmann · Journal of the American Chemical Society · 2021
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