研究论文
Dienyl Homoallyl Alcohols via Palladium Catalyzed Ene-Type Reaction of Aldehydes with 1,3-Dienes
Masahiro Fukushima, Daiki Takushima, Masanari Kimura
Nagasaki University
来源Journal of the American Chemical Society
年份2010
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摘要与影响
摘要 · 完整
The combination of Pd catalyst and Xantphos ligand in the presence of Et(3)B nicely promotes the allylation of aldehydes with conjugated dienes to provide dienyl homoallyl alcohols in excellent yields. The reaction occurs selectively at the C-C double bond bearing higher electron density.
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学术脉络
学科主题
化学Catalytic Cross-Coupling Reactions
Catalytic Alkyne Reactions · Asymmetric Synthesis and Catalysis
参考文献 43
Nickel-Catalyzed Homoallylation of Aldehydes in the Presence of Water and Alcohols We thank Mr. Y. Ohhama, NMR Facility, for his outstanding technical assistance. Financial support from the Ministry of Education, Science, Sports, and Culture, Japanese Government, Grant-in-Aid for Scientific Research B, is acknowledged.
被引 102Masanari Kimura, Akihiro Ezoe, Shuji Tanaka · Angewandte Chemie International Edition · 2001
Palladium-Catalyzed Reactions of Hypophosphorous Compounds with Allenes, Dienes, and Allylic Electrophiles: Methodology for the Synthesis of Allylic H-Phosphinates
被引 86Karla Bravo‐Altamirano, Isabelle Abrunhosa‐Thomas, Jean‐Luc Montchamp · The Journal of Organic Chemistry · 2008
Pd-Catalyzed Intermolecular Amidation of Aryl Halides: The Discovery that Xantphos Can Be Trans-Chelating in a Palladium Complex
被引 469Jingjun Yin, Stephen L. Buchwald · Journal of the American Chemical Society · 2002
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引用本文 34
Featuring Xantphos
被引 142Piet W. N. M. van Leeuwen, Paul C. J. Kamer · Catalysis Science & Technology · 2017
A Palladium Complex as an Asymmetric π-Lewis Base Catalyst for Activating 1,3-Dienes
被引 102Ben‐Xian Xiao, Bo Jiang, Ru‐Jie Yan · Journal of the American Chemical Society · 2021
Nickel‐Catalyzed Enantio‐ and Diastereoselective Three‐Component Coupling of 1,3‐Dienes, Aldehydes, and a Silylborane Leading to α‐Chiral Allylsilanes
被引 93Nozomi Saito, Ayami Kobayashi, Yoshihiro Sato · Angewandte Chemie International Edition · 2011
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