研究论文
Novel Synthesis of Hybrid Calixphyrin Macrocycles
Christophe Bucher, Daniel Seidel, Vincent M. Lynch, Vladimı́r Král, Jonathan L. Sessler
The University of Texas at Austin
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摘要与影响
摘要 · 完整
The reaction of benzaldehyde with excess pyrrole at room temperature in the absence of solvent affords a mixture of meso-substituted polypyrranes species. After separation by column chromatography, these may be used to prepare a range of calix[4]phyrin macrocycles by condensation with acetone under conditions of acid catalysis.
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学术脉络
学科主题
材料 / 化学Porphyrin and Phthalocyanine Chemistry
Supramolecular Chemistry and Complexes · Luminescence and Fluorescent Materials
参考文献 25
100 and more basic NMR experiments
被引 457Braun, Siegmar, Kalinowski, Hans-Otto, Berger, Stefan · TUbilio (Technical University of Darmstadt) · 1996
The first stable monocyclic phlorin free base. Preparation and X-ray structure determination of 5,21-dihydro-5,10,15,20,22-pentaphenylporphyrin (N-phenyl-meso-tetraphenylphlorin)
被引 27B�n�dicte Krattinger, H. J. CALLOT · Chemical Communications · 1996
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被引 75Julius Ephraim · Angewandte Chemie · 1926
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Chemistry of<i>meso</i>-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist
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被引 117Masatoshi Ishida, Yoshinori Naruta, Fumito Tani · Angewandte Chemie International Edition · 2009
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