Cycloaddition of CO<sub>2</sub> with epoxides and esterification reactions using the porous redox catalyst Co-POM@MIL-101(Cr)
Afsaneh Marandi, Mehrnaz Bahadori, Shahram Tangestaninejad, Majid Moghadam, Valiollah Mirkhani, Iraj Mohammadpoor‐Baltork, Robert Frohnhoven, Sanjay Mathur 等 10 位
University of Isfahan Institute of Catalysis and Petrochemistry University of Cologne
内容与影响
The catalytic activity of the Co-POM@MIL-101(Cr) composite in solvent-free cycloaddition of CO<sub>2</sub> to epoxides and esterification of acetic acid with alcohols is due to an outer-sphere electron transfer mechanism using the Co(<sc>iii</sc>)/Co(<sc>ii</sc>) redox pair.
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材料 / 化学Carbon dioxide utilization in catalysis
Metal-Organic Frameworks: Synthesis and Applications · CO2 Reduction Techniques and Catalysts
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