研究论文
Sustainable synthesis of CO 2 -derived polycarbonates from d -xylose
David K. Tran, Ahmed Z. Rashad, Donald J. Darensbourg, Karen L. Wooley
Texas A&M University
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摘要与影响
摘要 · 完整
Synthetic transformation of d -xylose into a four-membered cyclic ether allows for reactions with CO 2 leading to linear polycarbonates by either ring-opening copolymerisation directly or by isolation of a six-membered cyclic carbonate followed by ring-opening polymerisation.
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学术脉络
学科主题
材料 / 化学Carbon dioxide utilization in catalysis
biodegradable polymer synthesis and properties · Catalysis for Biomass Conversion
参考文献 63
Bio-based polycarbonate from limonene oxide and CO 2 with high molecular weight, excellent thermal resistance, hardness and transparency
被引 317Oliver Hauenstein, Marina Reiter, Seema Agarwal · Green Chemistry · 2015
Polycarbonates Derived from Glucose via an Organocatalytic Approach
被引 131K. Mikami, Alexander T. Lonnecker, Tiffany P. Gustafson · Journal of the American Chemical Society · 2013
Carbon Dioxide/Epoxide Coupling Reactions Utilizing Lewis Base Adducts of Zinc Halides as Catalysts. Cyclic Carbonate versus Polycarbonate Production
被引 114Donald J. Darensbourg, Samuel Lewis, Jody Rodgers · Inorganic Chemistry · 2002
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引用本文 37
Evolution of Copolymers of Epoxides and CO 2 : Catalysts, Monomers, Architectures, and Applications
被引 133Guan‐Wen Yang, Rui Xie, Yao‐Yao Zhang · Chemical Reviews · 2024
Enabling New Approaches: Recent Advances in Processing Aliphatic Polycarbonate‐Based Materials
被引 54Peiran Wei, Gulzar A. Bhat, Donald J. Darensbourg · Angewandte Chemie International Edition · 2023
The advent of recyclable CO 2 -based polycarbonates
被引 47Fabiana Siragusa, Christophe Detrembleur, Bruno Grignard · Polymer Chemistry · 2023
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