研究论文
Tandem isonitrile insertion/azacyclopropylidene-annulated cyclohexenone–tropone rearrangement of p -QMs and TosMIC: de novo synthesis of pyrrolotropones with anti-cancer activity
Chuan‐Hua Qu, Gui‐Ting Song, Jiuhong Huang, Run Qiu Huang, Yuan Chen, Tong Liu, Dianyong Tang, Zhigang Xu 等 9 位
Chongqing University of Arts and Sciences
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摘要与影响
摘要 · 完整
TosMIC causes ring expansion of p -QMs: highly substituted pyrrolotropones are rapidly assembled in a domino process mediated by DBU. The utility of the method was highlighted by follow-up transformation and biological activity identification.
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学术脉络
学科主题
化学Cyclopropane Reaction Mechanisms
Organic Chemistry Synthesis Methods · Synthesis and Characterization of Pyrroles
参考文献 86
Natural Tropolones and Some Related Troponoids
被引 5Tetsuo Nozoe · Springer eBooks · 1956
Progress in the chemistry of organic natural products, vol. 6
被引 119John R. Johnson · Archives of Biochemistry and Biophysics · 1952
A study of the norcaradiene–cycloheptatriene equilibrium in a series of azulenones by NMR spectroscopy; the impact of substitution on the position of equilibrium
被引 23Lorraine M. Bateman, Orla A. McNamara, N. Rachael Buckley · Organic & Biomolecular Chemistry · 2015
此处列出前 3 条
引用本文 10
Recent advances in the cyclization of para-quinone methides
被引 33Xianping Liu, Yining Ren, Longzhi Zhu · Tetrahedron · 2023
Metal‐Free Reductive Coupling of para‐Quinone Methides with 4‐Cyanopyridines Enabled by Pyridine‐Boryl Radicals: Access to Pyridylated Diarylmethanes with Anti‐Cancer Activity
被引 18Chuan‐Hua Qu, Lixia Gao, Yan Tang · Chemistry - A European Journal · 2022
Microwave-assisted copper catalyzed decarboxylative reductive coupling of para -quinone methides with 3-indoleacetic acids: rapid access to polycyclic spiroindolequinone derivatives
被引 12Gui‐Ting Song, Yuan Liu, Xin‐Yue Hu · Organic Chemistry Frontiers · 2023
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