研究论文
Catalytic asymmetric construction of planarly and centrally chiral [2.2]paracyclophanes by combining photochemical and cobalt-catalyzed desymmetrization
Lin-Hui Zhou, Yanxi Chen, Weiwei Chen, Yuan Ping Feng, Fang Ma, Kefeng Zhang
Huaibei Normal University
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摘要与影响
摘要 · 完整
photochemical cobalt-catalyzed desymmetrization. This reaction proceeds efficiently under mild conditions and exhibits broad functional group tolerance with high stereoselectivities, thus providing a platform for the synthesis of valuable multi-chiral PCPs.
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学术脉络
学科主题
化学Synthesis and Properties of Aromatic Compounds
Surface Chemistry and Catalysis · DNA and Nucleic Acid Chemistry
参考文献 54
Preparation and Structure of Di-p-Xylylene
被引 402Carolyn J. Brown, A. C. Farthing · Nature · 1949
Kinetic Resolution of rac -4,12-Dibromo[2.2]paracyclophane in a Palladium [2.2]PHANEPHOS Catalyzed Amination
被引 145Kai Rossen, Philip J. Pye, Ashok Maliakal · The Journal of Organic Chemistry · 1997
Macro Rings. I. Preparation and Spectra of the Paracyclophanes
被引 473Donald J. Cram, H. Steinberg · Journal of the American Chemical Society · 1951
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引用本文 6
Catalytic Asymmetric Reductive Amination for Planar Chiral [2,2]Paracyclophanes via Desymmetrization and/or Kinetic Resolution †
被引 7Yi Wang, Qin Shi, Zi‐Rou Hu · Chinese Journal of Chemistry · 2025
Desymmetrization of Pseudo ‐ para Diformyl[2.2]Paracyclophane via Brønsted Acid‐Catalyzed Reductive Amination
被引 4Sandip Baban Shinde, Martin Kamlar, Vojtěch Dočekal · Advanced Synthesis & Catalysis · 2026
Origin of stereoselectivity in NHC-catalyzed desymmetrization of pseudo- para -substituted [2.2]paracyclophane dialdehydes toward planar chirality
被引 4Yanqi Fan, Boya Dai, Peng Zhou · Catalysis Science & Technology · 2026
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