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On the synthesis and structure of reactive halonium ions
Lukas Fischer, Michael H. Lee, Anja Wiesner, Carsten Müller, Sebastian Riedel
Freie Universität Berlin
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Fluorinated diethyl and dipropyl halonium salts were synthesized via fluoroalkylation of bromofluoro and iodofluoro alkanes. Oxidation of CHCl(CH 3 )(CF 3 ) yielded a highly reactive asymmetric chloronium species, capable of isobutane activation.
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学科主题
物理Advanced Chemical Physics Studies
Mass Spectrometry Techniques and Applications · Inorganic Fluorides and Related Compounds
参考文献 33
Diaryliodonium Salts: A Journey from Obscurity to Fame
被引 1,178Eleanor A. Merritt, Berit Olofsson · Angewandte Chemie International Edition · 2009
Molecular association in 2-bromo-2-chloro-1,1,1-trifluoroethane (Halothane)
被引 18Anna Olejniczak, Andrzej Katrusiak, Pierangelo Metrangolo · Journal of Fluorine Chemistry · 2008
Stable Bromonium and Iodonium Ions of the Hindered Olefins Adamantylideneadamantane and Bicyclo[3.3.1]nonylidenebicyclo[3.3.1]nonane. X-Ray Structure, Transfer of Positive Halogens to Acceptor Olefins, and ab Initio Studies
被引 160R. S. Brown, Richard W. Nagorski, Andrew J. Bennet · Journal of the American Chemical Society · 1994
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Trendbericht Anorganische Chemie 2026: Hauptgruppen‐ und Molekülchemie
被引 0Fabian Dankert, Oliver P. E. Townrow · Nachrichten aus der Chemie · 2026
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