研究论文
Study of the monocarbonate complex of pentavalent neptunium (NH4)[NpO2(CO3)]
М. С. Григорьев, Н.А. Буданцева, А. М. Федосеев
Russian Academy of Sciences Frumkin Institute of Physical Chemistry and Electrochemistry
来源Russian Journal of Coordination Chemistry
年份2010
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摘要 · 完整
The single crystals of the Np(V) complex (NH 4 )[NpO 2 (CO 3 )] ( I ) were synthesized and studied by X-ray diffraction. At 100 K, the crystals are hexagonal, space group P 6 3 μmc, a = 5.0734(1) Å, c = 10.9191(2) Å, V = 243.399(11) Å 3 , Z = 2, ρ(calcd) = 4.735 g/cm 3 . The absorption spectra of a crystal of I in the visible and infrared ranges were measured.
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学术脉络
学科主题
化学Radioactive element chemistry and processing
Lanthanide and Transition Metal Complexes · Nuclear materials and radiation effects
参考文献 17
REFINEMENT OF THE CRYSTAL STRUCTURE OF RUTHERFORDINE
被引 75Robert J. Finch, Matthew A. Cooper, F. C. Hawthorne · The Canadian Mineralogist · 1999
Modelling of uranium and neptunium chemistry in a deep rock environment
被引 4Ir�ne Lund�n, Karin Andersson, Gunnar Skarnemark · Aquatic Geochemistry · 1997
Alkali Carbonates of Np(V), Pu(V) and Am(V)
被引 35J. P. Nigon, R. A. Penneman, Eugene. Staritzky · The Journal of Physical Chemistry · 1954
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引用本文 4
XAS and TRLIF spectroscopy of uranium and neptunium in seawater
被引 39Melody Maloubier, Pier Lorenzo Solari, Philippe Moisy · Dalton Transactions · 2015
Synthesis, crystal structure, and spectra of the Np(V) terephthalate [C(NH2)3]3[NpO2(C6H4(COO)2)2]·5H2O and An(VI) terephthalates [AnO2(C6H4(COO)2)] (An = U, Np, Pu)
被引 6I. A. Charushnikova, Н.А. Буданцева, А. М. Федосеев · Radiochemistry · 2015
Formation of Neptunium(V) Carbonates: Examining the Forceful Influence of Alkali and Alkaline Earth Cations
被引 5Anastasiia S. Kuzenkova, Tatiana V. Plakhova, Iurii M. Nevolin · Inorganic Chemistry · 2023
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