广州市大气颗粒物PM 2.5 显微形貌特征和来源解析

PM2.5 is the primary pollutant which has influenced the urban atmospheric environment in recent years, and its genetic mechanism is complicated. The microscopic morphology and trace element concentration of PM2.5 in the Guangzhou urban area were determined by Scanning Electron Microscope and Inductively Coupled Plasma-Mass Spectrometry, respectively. The enrichment factor method was adopted to constrain the source of PM2.5. The results show that PM2.5 mainly occurs as amorphousness fine particles. A silicate combination containing Fe, Mg, Al, K and Na is the main chemical composition of PM2.5, characterized by the first fine particles from road dust and buildings. An energy spectrum diagram of single amorphous particle shows the combination characteristics of sulfate and nitrate. These particles may have been secondary fine particles formed from pollution gases of SO2 and NOx from automobile exhaust in the atmospheric environment, through the nucleation induced phase behavior change under specific physical and chemical conditions. Heavy metals were highly enriched in PM2.5, including Cd, Se, Zn, Cu, Pb, and As. Local widespread use of deca bromine biphenyl ether as a flame retardant and a large number of E-waste dismantling are the main factors for abnormal enrichment of Br in the fine particles. The concentration of rare earth elements ranges from 0.022 to 0.582 ng/m3, with the relative enrichment of heavy rare earth elements in PM2.5. These features indicate that the composition of PM2.5 in the Guangzhou urban area are not only made up of primary particles, but also made up of secondary particles, characterized by multiple sources.